Position a rack in the center of your oven. Preheat your oven to 350 degrees (F). Line a 9x5-inch loaf pan with parchment paper, so that two of the sides overlap the pan. Spray the bottom and sides of the pan with nonstick baking spray.
In a large bowl, sift together the flour, cocoa powder, baking soda, salt, cinnamon, and espresso powder. Set aside.
In the bowl of a stand mixer fitted with the paddle attachment, or in a large bowl using a handheld electric mixer, beat the butter until smooth and creamy, about 1 minute. Gradually add in the sugar and beat on medium-high speed until well combined, about 2 minutes. Stop the mixer and scrape down the sides and bottom of the bowl, then beat for another 30 seconds.
Add in the eggs, one at time, beating well after each addition and scraping down the sides and bottom of the bowl as needed.
On low speed, add in the mashed banana and vanilla, beating until just incorporated in the mix.
Staying on low speed, add in the flour mixture in three additions, alternating with the sour cream in two additions, beginning and ending with the flour. Mix until just combined!
Using a rubber spatula, fold in the chocolate chips. Then scrape the batter into the prepared pan and smooth the top with a spatula.
Bake for 55 to 65 minutes, or until a cake tester inserted in the center comes out clean (other than melted chocolate or a few moist crumbs). Cool in the cake pan, on a wire rack, for 30 minutes.
Unmold the cake onto the cooling rack, turn the cake right side up, and cool completely.